WATER QUALITY IN KENTUCKY:
SUMMARY SHEET, USING ACTIVATED CARBON FILTERS TO TREAT HOME DRINKING
WATER
ISSUED: 9-90
REVISED:
Joe Taraba; Linda Heaton; Tom Ilvento
The U.S. Environmental Protection Agency
(EPA) has defined three general categories of filters for treating home
drinking water: water filters, bacteriostatic water filters and water purifiers.
1) Water filters, generally comprised of activated carbon (AC),
are intended to remove rust; sediment; organic compounds that impart a
taste, odor or color; chlorine and some other contaminants. They are not
designed remove or destroy bacteria unless they are labeled water purifiers.
2) Bacteriostatic water filters: These filters, also comprised
of AC, generally remove the same contaminants as water filters, but they
contain an additional chemical agent, such as silver ions, that hinders
the growth of bacteria trapped within the filter itself. (Bacteriostatic
means the ability to inhibit the further growth of bacteria.)
3) Water purifiers are designed to treat raw water to make it
suitable for human consumption. They must kill or remove essentially all
bacteria, protozoa and protozoan cysts that the label or instructions claim
to remove.
Water purifiers are further subdivided
as pesticidal devices and pesticides. As used here, the words pesticide
and pesticidal shouldn't be confused with chemicals used in agriculture
or households to control weeds, insects, molds or bacteria. Here the words
mean an agent that destroys a pest. In this case the pest is bacteria that
cause disease.
a) pesticidal devices purify water by physical or mechanical
means, such as filtration, heating, etc.
b) pesticides purify water through the use of antimicrobial
agents (such as iodine) contained in the product.
Mechanical Water Filters
A mechanical water filter removes sediment
(particulate) by a mechanical process based on physical size of the particulate.
It can remove inorganic contaminants, such as heavy metals, if they are
in the particulate form and not dissolved in the water and if the particulate
is large enough for the filter medium to retain.
Most heavy metals found in drinking
water, particularly lead, rarely occur there naturally. They come most
likely from the water distribution system or from brass fittings, faucets
or household plumbing that is copper with lead solder.
Mechanical filters include depth filters
and surface filters. A depth filter consists of an array of filter material,
with openings of decreasing size between the material. Sediment is trapped
throughout the depth. It is rated according to the approximate particle
size (in microns) that it will retain (I micron is approximately 0.00004
inches). This rating is not an absolute. An unknown percentage of particles
larger than the rating will pass through, while some particles smaller
than the rating will be retained.
You would choose a depth filter when
particulate loads are high (i.e., when there are visible and settleable
particles) or when you need to filter out a large amount of particulates
without clogging the filter.
Surface filters have an advantage over
depth filters because the size of the retained particle can be defined
more precisely, but they clog more readily than depth filters. Usually
they are preceded by a depth filter.
How Activated Carbon Structure Works
The majority of water filters purchased
today contain activated carbon or charcoal (AC). Some devices contain AC
but make no claim that it is present. The only way the consumer can determine
its presence may be to break open the devices, thus destroying their effectiveness.
AC has an immense surface area. A single
gram can have a total surface area of more than 1,000 sq. ft. AC is extremely
adsorptive (able to attract minute particles so they stick to the surface).
It can effectively remove organic compounds, chlorine and dissolved radon.
Carbon filters will not remove bacteria, calcium and magnesium (hard water),
fluorides, nitrates, chlorides and many other inorganic chemicals. Only
a very specific type of AC can effectively adsorb heavy metals.
The molecules that are removed sink
into the AC pores and eventually stick to the internal surfaces (see Figure
1).
Activated Carbon Filter Types
Four types of AC filters are marketed
as home treatment devices (see Figures 2A to 2D).
1) Faucet filters:
•These slip over the mouth of the water
faucet. Two basic designs are the bypass and the no-bypass:
•Bypass: has a valve that allows you
filter only the water used for cooking and drinking (prolongs the life
of the filter).
•no-bypass: filters all the water flowing
through the faucet.
2) Pour-throughs:
•These are the simplest and most portable.
They require no installation at all. You simply hold the filter over a
container and pour in tap water.
3) In-line or stationary:
•Tapped into the cold-water pipe, these
filter all the water flowing through the pipe.
4) Line bypass:
•These are installed by cutting into
the water line beneath the sink. A separate faucet attached to the sink
delivers filtered water for drinking and cooking, but unfiltered water
can still be drawn from the regular faucet.
Factors Affecting Activated Carbon Fitter Performance
The following factors seem to affect
the performance of AC filters, and consumers should investigate them before
choosing an AC filter:
1)water contact time with AC
2)iodine number
3)particle size of the AC
4)manufacturer's recommended
water volume treatment capacity
5)tests and ratings of independent
organizations
Contact Time.
This is the time it takes water to
flow through the device. Contact times can vary from one second to two
minutes. The longer the contact time, the more chance for the chemicals
to stick to the AC.
Iodine number.
One measure of AC's capacity to remove
organics is the iodine number. This is the amount of iodine in milligrams,
adsorbed by one gram of AC at a standard set of conditions. The higher
the iodine number, the more adsorptive the AC. Such a number is rarely
reported in the advertising literature or instructions or on box labels
of AC devices.
Particle Size.
The smaller the particle size, the
more outside surface is available for compounds to enter the AC, resulting
in a higher removal rate of organic contaminants.
Recommended Capacity.
Some manufacturers of AC water treatment
devices give a recommended water treatment capacity in gallons. When the
rated capacity is exceeded, they recommend replacing the AC.
Most devices on the market do not indicate
how much water has passed through the filter during use. A consumer can
estimate the number of days a filter will last before needing replacement.
Assume that each person uses one gallon of water each day for drinking
and one to three gallons a day for cooking. To illustrate, if a household
of four people used one gallon per person per day, four gallons of water
will need to be treated. At this rate of use, an AC treatment device with
a 200-gallon capacity will last about 50 days (200 gal./4 gal. a day).
Table 1. Performance Factors and Removal Efficiency for Selected
AC.
|
Manufacturer's
rated capacity
(gallons) |
Amount
of carbon
(grams) |
Iodine
number
of carbon |
Contact
time
(seconds) |
Average %
Removal
of THM |
Average %
Removal
of NPTOC |
Average %
Removal of
Halogenated
Hydrocarbons |
Line by-pass |
Culligan SG-2 |
4,000 |
1,708 |
980 |
39 |
89 |
28 |
99 |
Aquacell Bacteriostatic |
2,000 |
417 |
867 |
13 |
86 |
23 |
97 |
Aqualux CB-2 |
2,000 |
1,150 |
966 |
35 |
98 |
23 |
99 |
Everpure QC4-THM |
1,000 |
765 |
1,010 |
43 |
99 |
55 |
99 |
Seagull IV |
1,600 |
300 |
434 |
15 |
70 |
41 |
97 |
Faucet-mounted |
Hurley Town & Country |
4,000 |
895 |
913 |
36 |
69 |
31 |
97 |
Aqua Guard ACT31 |
500 |
51 |
1,275 |
3 |
43 |
12 |
Instapure FI-C |
200 |
27 |
|
1.6 |
24 |
11 |
Stationary |
AMF Cuno-IM |
3,000 |
395 |
870 |
3.6 |
34 |
7 |
Pour-through |
Filbrook |
1,000 |
97 |
788 |
44 |
40 |
14 |
94 |
Source: GSRI Study for EPA, 1984. THM: trihalomethanes. NPTOC: Non-purgeable
total organic carbon.
For more detailed information see Extension publication IP-6.
Table 2. Activated Carbon Filters - Cost Comparisons.
Manufacturer |
Model |
Cost |
Replacement
Filter Cost
(each) |
Filter Rated
Capacity (gal.) |
Chloroform
Removal (%) |
High Volume Filters |
Ametek |
CCF-201 |
$158 |
$20 (2 req'd) |
1500 |
>97 |
Amway |
E-9230 |
276 |
69 |
5000 |
>97 |
Culligan |
Supergard THM |
349 |
37 |
1000 |
90 |
Cuno |
Aqua Pure AP-CRF |
155 |
15 |
450 |
90 |
Everpure |
H200 |
298 |
90 |
750 |
>97 |
Filterite |
CF-10 |
85 |
8 |
750 |
90 |
Kinetico |
MAC |
275 |
32 |
500 |
90 |
NSA |
Bacteriostatic 50C |
179 |
|
5000 |
80 |
Omni |
UC-2 |
99 |
20 (2 req'd) |
|
80 |
Faucet-Mounted |
Cuno |
PP01105 |
30 |
6 |
735 |
60 |
Pollenex |
WP90K |
22 |
5 |
200 |
30 |
Pour-Through |
Brita |
|
30 |
8 |
35 |
65 |
Innova |
|
7 |
5 |
30 |
45 |
Glacier Pure |
|
13 |
5 |
100 |
40 |
Source: Consumer Reports (Jan. 1990) and National Sanitation Foundation.
Independent Performance Ratings:
Several independent consumer testing
organizations have rated the performance of AC filters. These reports are
the source for the information shown at Tables 1 and 2.
Validation of Performance Claims
The National Sanitation Foundation
(NSF) validates manufacturers' claims if they voluntarily submit their
units for testing and if their devices meet NSF standards for the specific
compound the manufacturer claims to remove.
The NSF tests treatment devices for
two separate factors: 1) chemicals that affect only the aesthetics (i.e.,
taste, odor, color and appearance) of drinking water and 2) hazardous chemicals.
The outflow from these units must meet the EPA Secondary Drinking Water
Regulations while processing the water up to the device's rated capacity.
The devices must be periodically tested to certify that they continue to
meet claims. Those devices meeting certain standards are allowed to display
the NSF Mark on the device, literature and advertising.
NSF also tests and certifies treatment
devices that claim to reduce hazardous chemicals in drinking water for
the rated capacity, i.e. those chemicals that exceed the EPA Primary Drinking
Water Standards or those chemicals that are suspected to cause illness
but for which there is no EPA standard.
The NSF requires that the manufacturers
of tested equipment provide a means (possibly an indicator or warning)
to alert the consumer when the unit is not performing properly. These may
be on the device (e.g., an automatic shut-off, a reduction in flow, an
alarm) or in a separate test kit provided to the consumer.
To be approved by NSF, AC filter units
that do not provide a means to alert the consumer must remove the contaminants
for twice the rated capacity. This gives a safety factor to the consumer.
NSF also evaluates bacteriostatic devices.
It tests 1) whether the bacterial population is any greater in the water
coming out of the device than in the water coming in and 2) whether the
active bacteriostatic agent or its degradation product exceeds EPA's Primary
Drinking Water Regulations or those of any other federal regulatory agency
for chemicals not regulated by EPA.
Radon Gas
Scientists know that AC can remove
99 percent of radon gas dissolved in water, but they have not yet established
efficiency rates for radon removal for commercially available drinking
water treatment devices.
Bacterial Growth
AC units have several drawbacks. Because
AC deactivates it, chlorine cannot disinfect bacteria present in the AC.
However, if water is treated to eliminate disease-causing bacteria before
it reaches the device, these bacteria do not grow and multiply on the AC.
But non-pathogenic bacteria, in particular
heterotrophic plate count (HPC) bacteria, will grow. The health effects
of high counts of HPC bacteria are not clear. We take in millions of bacteria
a day, normally with no ill effects, and a healthy person is generally
not at risk. But there may be a potential health risk for those who a more
vulnerable, such as the aged, the very young or the sick whose immune systems
are weaker. Certain HPC bacteria are known to be 41 opportunistic" and
may take advantage of these weaknesses and cause illness.
A high bacterial count can occur overnight
when water does not pass through an AC filter. The first water drawn from
the filter that day may be cloudy with bacteria. Flushing the filter at
full flow for 30 seconds reduces the HPC bacteria counts to 1/7 the initial
numbers, and as the AC filter is used during normal household activity
for four hours, the HPC bacteria are reduced by 1/25. Still, several studies
indicate that the HPC bacteria count is higher in water coming out of the
device than in water coming in.
One promoted solution may be a bacteriostatic
filter. The AC in bacteriostatic filters is impregnated with silver to
prevent HPC bacterial accumulations. The silver is a disinfectant, and
when released or leached from the AC in small quantities, it interacts
with the bacteria in the filter and reduces their ability to multiply.
The silver, a heavy metal, should be released in small enough quantities
so as not to exceed the toxic limits set forth by the EPA Primary Drinking
Water Regulations.
Studies have indicated that silver-impregnated
AC made little difference in reducing HPC bacteria except for the first
month of use when bacterial counts were lower than AC without silver.
The best recommendation for preventing high HPC bacteria counts is
to replace the AC filter at least as often as the manufacturer recommends
or even more frequently. If the manufacturer makes no recommendation, replace
the AC at least every three months even if the manufacturer's recommended
treatment capacity is not exceeded. Otherwise, the owner should follow
the manufacturer's recommendations for changing the AC.
When an AC Filter Is No Longer Effective
Another disadvantage of an AC filter
is that the only way to be sure the filter has reduced the contaminants
of concern is to test the water coming out of the filter which is expensive
unless the manufacturer provides a testing procedure. You will be aware
of the loss of effectiveness because of an "off' taste, odor or color in
the water, but many hazardous chemicals cannot be detected in this way.
Recommendations
•Use AC filters to treat water only
for drinking and cooking unless radon removal is required.
•Use AC filters on water that is disinfected
before it reaches the filter.
•Use AC filters on cold water only.
•Replace the filter: - if signs of
sediment appear in treated water. - if taste, odor or color changes. This
can mean that the AC is no longer effectively removing the compounds. -
when the flow is noticeably reduced
•Filter the water at the slowest possible
rate tolerable to increase contact time.
•Flush filters for 30 seconds when
first used each day. Flush the filter for two or three minutes if not used
for several days.
•Change the AC filter:
- As frequently as the manufacturer
recommends -- preferably more often. If there is no recommendation, change
the filter every three months even if the water treatment capacity is not
exceeded.
- When treatment capacity is reached.
Estimate use at one gallon of water per person per day for drinking and
two gallons per person per day for drinking and cooking.
•Select AC filters whose claims are
independently validated by a nationally recognized independent testing
laboratory.
•Silver-impregnated filters reduce
bacteria on filters for up to four weeks, then give similar results as
other AC filters.
This material is based on work supported
by the U.S. Department of Agriculture, Extension Service, under special
project number 89 -FWQI-1-9156.
Trade names are used for comparison
purposes only. No endorsement is intended, nor is criticism implied of
similar products not named.